| 以反丁烯二酰氯桥联的10,15,20-三（对-氯代苯基）卟啉二联体及其配合物的合成与性质研究 |
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| 引用本文： | 孙园园,连文慧,王建成,王彬彬,单凝,于连香,于苗,师同顺.以反丁烯二酰氯桥联的10,15,20-三（对-氯代苯基）卟啉二联体及其配合物的合成与性质研究[J].化学学报,2011,69(20):2465-2470. |
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| 作者姓名： | 孙园园 连文慧 王建成 王彬彬 单凝 于连香 于苗 师同顺 |
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| 作者单位： | 1. 吉林大学化学学院,长春,130021
2. 吉林大学机械科学与工程学院,长春,130025 |
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| 基金项目： | 国家自然科学基金(No.20801022)资助项目 |
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| 摘 要： | 用5-（对-羟基苯基）-10,15,20-三（对-氯代苯基）卟啉为原料合成了以反丁烯二酰氯桥连的10,15,20-三（对-氯代苯基）卟啉二联体及其Zn,Cu,Co,Mn配合物,并用红外光谱、拉曼光谱、紫外光谱、质谱、核磁共振谱对其结构进行了表征.利用分子荧光光谱和表面光电压对其光学性质进行了研究.
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| 关 键 词： | 卟啉 反丁烯二酰氯 二联体 合成 配合物 荧光 |
Synthesis and Characterization of (E)-2-Butenedioyl Dichlorid Bridge-linked 10,15,20-Tri(p-chlorophenyl)porphyrin Dimer and Its Complexes |
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| Sun,Yuanyuana Lian,Wenhuia Wang,Jianchengb Wang,Binbina Shan,Ninga Yu,Lianxianga Yu,Miao,a Shi,Tongshun,a.Synthesis and Characterization of (E)-2-Butenedioyl Dichlorid Bridge-linked 10,15,20-Tri(p-chlorophenyl)porphyrin Dimer and Its Complexes[J].Acta Chimica Sinica,2011,69(20):2465-2470. |
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| Authors: | Sun Yuanyuana Lian Wenhuia Wang Jianchengb Wang Binbina Shan Ninga Yu Lianxianga Yu Miao a Shi Tongshun a |
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| Institution: | Sun,Yuanyuana Lian,Wenhuia Wang,Jianchengb Wang,Binbina Shan,Ninga Yu,Lianxianga Yu,Miao,a Shi,Tongshun,a(a College of Chemistry,Jilin University,Changchun 130021)(b College of Mechanics,Changchun 130025) |
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| Abstract: | The 10,15,20-tri(p-chlorophenyl)porphyrin dimer was synthesized with(E)-2-butenedioyl di-chlorid as a bridge-linked reagent and its Zn,Cu,Co,Mn complexes were synthesized and characterized by means of IR,Raman,UV-Vis,MS,1H NMR and 13C NMR.The optical properties were studied by fluores-cence spectrometer and SPS(surface photovoltage spectroscopy). |
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| Keywords: | porphyrin (E)-2-butenedioyl dichlorid dimer synthesis complex fluorescence |
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