Schiff碱配合物的研究II: 一些Fe(III)配合物的磁性质与电化学行为 |
| |
引用本文: | 汪信,KOTUN,M.E.,FANNING,J.C.Schiff碱配合物的研究II: 一些Fe(III)配合物的磁性质与电化学行为[J].化学学报,1990,48(2):204-207. |
| |
作者姓名: | 汪信 KOTUN M.E. FANNING J.C |
| |
作者单位: | 华东工学院近代化学研究室;美国克莱姆森大学化学系 |
| |
摘 要: | Fe(III)schiff碱配合物的磁性质和电化学还原性是该类配合物的基本特性, 本文研究三种配合物, 单核高自旋配合物, 单核低自旋配合物以及氧桥双核配合物的核磁共振性质电化学还原性。
|
关 键 词: | 铁络合物 核磁共振 席夫碱 磁性 电化学 |
Studies on schiff base complexes: II, magnetic and electrochemical behaviors of some iron (III)complexes |
| |
Abstract: | The magnetic and electrochem. properties of Fe(III) complexes Fe(salen)NO2, Fe(salen)NO3]2, Fe(salen)(SCN), KFe(salen)(CN)2], Fe(salen)]2O and Fe(5-NO2 saldpt]2O, where salen = salicylidene-ethylenediamine and saldpt = salicylidene-propylenediamine, were studied. The NMR chem. shifts and the Moessbauer spectra parameters were determine experimental The oxidation- behavior was studied by cyclic voltammetry. The effects of m-oxo bridging on the structure and electrochem properties were studied. |
| |
Keywords: | IRON COMPLEX NUCLEAR MAGNETIC RESONANCE SCHIFF BASE MAGNETISM ELECTROCHEMISTRY |
本文献已被 维普 等数据库收录! |
| 点击此处可从《化学学报》浏览原始摘要信息 |
| 点击此处可从《化学学报》下载免费的PDF全文 |
|