| 合成高分子作为手性固定相在高效液相色谱中的应用 |
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| 引用本文： | 王辉,徐晓冬.合成高分子作为手性固定相在高效液相色谱中的应用[J].高分子通报,2011(1):94-99. |
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| 作者姓名： | 王辉 徐晓冬 |
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| 作者单位： | 高分子材料研究中心哈尔滨工程大学材料科学与化学工程学院; |
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| 基金项目： | 哈尔滨市科技创新人才研究专项资金项目(2008RFQXG034) |
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| 摘 要： | 具有旋光活性的合成高分子基于它的手性结构而具有广泛的应用,其中最实际和广泛的应用是在高效液相色谱中作为手性固定相来拆分对映异构体,目前已成为合成化学、分析化学以及制药化学领域必不可少的分离材料.本文简要介绍了高效液相色谱手性固定相拆分法,综述了合成高分子,包括加聚物特别是聚甲基丙烯酸酯类和聚甲基丙烯酰胺类聚合物、聚酰胺...
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| 关 键 词： | 合成高分子 手性固定相 高效液相色谱 手性分离 |
Application of Synthetic Polymers as Chiral Stationary Phase in High Performance Liquid Chromatography |
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| WANG Hui,XU Xiao-dong.Application of Synthetic Polymers as Chiral Stationary Phase in High Performance Liquid Chromatography[J].Polymer Bulletin,2011(1):94-99. |
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| Authors: | WANG Hui XU Xiao-dong |
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| Institution: | WANG Hui,XU Xiao-dong(Polymer Materials Research Center,College of Materials Science and Chemical Engineeting,Harbin Engineering University,Harbin 150001,China) |
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| Abstract: | Optical active synthetic polymers were widely applied based on their chiral structure.The most practical and extensive application of them was using as chiral stationary phases(CSP) in high performance liquid chromatography(HPLC) for the resolution of enantiomers.Recently,optical active synthetic polymers have become necessary separation materials in the fields of synthetic chemistry,analytical chemistry and pharmaceutics.In this paper,the resolution method of enantiomers by CSP in HPLC was briefly introduc... |
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| Keywords: | Synthetic polymer Chiral stationary phase High performance liquid chromatography Chiral separation |
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