| 点击化学法修饰氧化石墨烯及其在高分子中的应用研究 |
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| 引用本文： | 熊军,杨雪颖,彭少贤,赵西坡.点击化学法修饰氧化石墨烯及其在高分子中的应用研究[J].高分子通报,2017(6). |
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| 作者姓名： | 熊军 杨雪颖 彭少贤 赵西坡 |
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| 作者单位： | 湖北工业大学材料科学与工程学院,绿色轻工材料湖北省重点实验室,绿色轻质材料与加工协同创新中心,武汉430068 |
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| 基金项目： | 国家自然科学基金，湖北省科技厅重点新产品新工艺项目 |
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| 摘 要： | 点击化学是一种操作简单方便、灵活高效的化学合成方法,对石墨烯的改性具有高效和活性位点可控等特点,是一种新型高效修饰石墨烯的改性法。本文结合点击化学改性石墨烯的特点及在高分子中的应用,将点击化学功能化修饰石墨烯分为共价键点击功能化和非共价键点击功能化,其中共价键结合又可细分为边缘点击功能化改性和表面点击功能化改性。本文介绍了叠氮功能改性剂的制备方法及其修饰石墨烯的点击反应原理,总结了点击功能化石墨烯及氧化石墨烯高分子复合材料的功能特性和应用前景。
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| 关 键 词： | 石墨烯 氧化石墨烯 点击化学 功能化 高分子复合材料 |
Click Chemistry Method Modification of Graphene Oxide and its Application in Polymer |
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| XIONG Jun,YANG Xue-ying,PENG Shao-xian,ZHAO Xi-po.Click Chemistry Method Modification of Graphene Oxide and its Application in Polymer[J].Polymer Bulletin,2017(6). |
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| Authors: | XIONG Jun YANG Xue-ying PENG Shao-xian ZHAO Xi-po |
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| Abstract: | Click chemistry is a method for chemical synthesis which is simple,convenient,flexible and efficient.And it is a new and efficient way in modifying graphene,which has the characteristics of high efficiency and controllable active site.The click chemistry functional modification for graphene was divided into covalent bonding method and non-covalent bonding method.Covalent bonding method was subdivided into click functional edge and surface modification.In this paper,preparation method of the functional modified agent of the azide and the click reaction principle of the modified graphene were introduced,and the potential application of click chemistry functionalized graphene and graphene oxide polymer composite was summarized. |
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| Keywords: | Graphene Graphene oxide Click chemistry Functionalization Polymer composites |
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