| 应用Diels-Alder反应制备聚合物的研究进展 |
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| 引用本文： | 杨哲,魏宏亮,楚晖娟,朱靖,李志成.应用Diels-Alder反应制备聚合物的研究进展[J].高分子通报,2010(1). |
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| 作者姓名： | 杨哲 魏宏亮 楚晖娟 朱靖 李志成 |
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| 作者单位： | 河南工业大学化学化工学院,郑州,450001 |
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| 基金项目： | 国家自然科学基金项目资助(50773018);;河南省教育厅自然科学基金项目资助(2008A430003);;郑州市科技局资助 |
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| 摘 要： | 由于Diels-Alder反应具有一系列重要特点(原子经济性、热可逆性、立体选择性、立体专一性和区域选择性等),自从1928年被发现以来,该反应就一直是人们研究的热点。将其应用于聚合物的合成中,可制备一些具有特殊性能的Diels-Alder聚合物,人们在这方面作了大量的研究工作,取得了许多研究成果。本文首先根据不同的分类标准,对应用Diels-Alder反应制备聚合物的研究进行了分类,然后结合本课题组的相关研究工作,综述了近年来人们在该领域的研究进展,最后展望了其研究前景。
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| 关 键 词： | Diels-Alder聚合物 手性 可逆性 自修复 水凝胶 |
Research Progress in the Preparation of Polymer Based on Diels-Alder Reaction |
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| YANG Zhe,WEI Hong-liang,CHU Hui-juan,ZHU Jing,LI Zhi-cheng.Research Progress in the Preparation of Polymer Based on Diels-Alder Reaction[J].Polymer Bulletin,2010(1). |
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| Authors: | YANG Zhe WEI Hong-liang CHU Hui-juan ZHU Jing LI Zhi-cheng |
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| Institution: | School of Chemistry and Chemical Engineering;Henan University of Technology;Zhengzhou 450001;China |
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| Abstract: | Diels-Alder reaction has been a hot topic in academe ever since its discovery in 1928 due to its important properties,such as atom economy,thermo-reversibility,regioselectivity,stereospecificity and stereoselectivity.Diels-Alder polymer is obtained by utilizing Diels-Alder reaction in polymer preparation,in which a lot of work has been done.In this paper,research progress in this field is classified from different stand point,and then is summarized,including our relative work in the field.Finally,the develo... |
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| Keywords: | Diels-Alder polymer Chiral Reversibility Self-healing Hydrogels |
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