Transition metals on the (0 0 0 1) surface of graphite: Fundamental aspects of adsorption,diffusion, and morphology |
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| Institution: | 1. The Ames Laboratory, Ames, IA 50011, USA;2. Department of Chemistry, Iowa State University, Ames, IA 50011, USA;3. Department of Physics & Astronomy, Iowa State University, Ames, IA 50011, USA;4. Department of Materials Science & Engineering, Iowa State University, Ames, IA 50011, USA;5. Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China;1. Faculty of Physics, Astronomy and Applied Computer Science, Jagiellonian University, Ul. S. Łojasiewicza 11, 30-348 Krakow, Poland;2. Department of Physics, University of Basel, Klingelbergstrasse 82, 4056 Basel, Switzerland;1. Campus Avançado Jandaia Do Sul, Universidade Federal Do Paraná, 86900-000, Jandaia Do Sul, PR, Brazil;2. Instituto de Física, Universidade Federal de Goiás, Campus Samambaia, 74690-900, Goiânia, GO, Brazil;3. Instituto de Física, Universidade Federal de Uberlândia, C. P. 593, 38400-902, Uberlândia, MG, Brazil;1. Department of Physical Chemistry and Materials Science, University of Szeged, Szeged, Hungary;2. Department of Applied and Environmental Chemistry, University of Szeged, Szeged, Hungary;3. MTA–SZTE Reaction Kinetics and Surface Chemistry Research Group, Szeged, Rerrich B. tér 1, H-6720 Szeged, Hungary;1. Department of Biophysical Microstructures, Institute of Nuclear Physics, Polish Academy of Sciences, PL-31342 Kraków, Poland;2. Institute of Physics, Faculty of Materials Engineering and Technical Physics, Poznan University of Technology, Piotrowo 3, 60-965 Poznań, Poland;3. M. Smoluchowski Institute of Physics, Jagiellonian University, Łojasiewicza 11, 30-348, Kraków, Poland;4. Department of Histology, Jagiellonian University Medical College, Kopernika 7, 31-034, Kraków, Poland;5. Chair of Medical Biochemistry Jagiellonian University Medical College, Kopernika 7, 31-034 Kraków, Poland;1. Department of Chemical Engineering, Louisiana State University, Baton Rouge, LA 70803, United States;2. Department of Physics and Astronomy, Louisiana State University, Baton Rouge, LA 70803, United States |
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| Abstract: | In this article, we review basic information about the interaction of transition metal atoms with the (0 0 0 1) surface of graphite, especially fundamental phenomena related to growth. Those phenomena involve adatom-surface bonding, diffusion, morphology of metal clusters, interactions with steps and sputter-induced defects, condensation, and desorption. General traits emerge which have not been summarized previously. Some of these features are rather surprising when compared with metal-on-metal adsorption and growth. Opportunities for future work are pointed out. |
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| Keywords: | Graphite Graphene Transition metal Nucleation Adsorption Diffusion |
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