Site characteristics in metal organic frameworks for gas adsorption |
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Authors: | Alper Uzun Seda Keskin |
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Institution: | Department of Chemical and Biological Engineering, Koç University, Rumelifeneri Yolu, Sariyer, 34450 Istanbul, Turkey; KÜTEM (Koç University TÜPRA? Energy Center), Koç University, Rumelifeneri Yolu, Sariyer, 34450 Istanbul, Turkey |
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Abstract: | Metal organic frameworks (MOFs) are a new class of nanoporous materials that have many potential advantages over traditional nanoporous materials for several chemical technologies including gas adsorption, catalysis, membrane-based gas separation, sensing, and biomedical devices. Knowledge on the interaction of guest molecules with the MOF surface is required to design and develop these MOF-based processes. In this review, we examine the importance of identification of gas adsorption sites in MOFs using the current state-of-the-art in experiments and computational modeling. This review provides guidelines to design new MOFs with useful surface properties that exhibit desired performances, such as high gas storage capacity, and high gas selectivity. |
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Keywords: | Metal organic framework Gas adsorption Adsorption sites |
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