Catalytic conversion of defatted rice bran into value added chemicals using copper ferrite: A sustainable approach |
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Institution: | 1. Department of Chemistry, School of Sciences, Jain University, JC Road, Bangalore, 560027, Karnataka, India;2. Green Chemistry Centre, PES University, Outer Ring Road, BSK III Stage, Bangalore, 560085, Karnataka, India;3. Department of Physics, Faculty of Engineering & Technology, Jain University, Bangalore, 562112, Karnataka, India;1. Department of Chemistry, Basaveshwar Engineering College, Bagalkot, Karnataka 587102, India;2. Centre for Nano and Material Sciences, Jain (Deemed-to-be-University), Jain Global Campus, Kanakapura, Bangalore, Karnataka 562112, India;1. Department of Chemistry, GLA University, Mathura, 281406, U.P., India;2. Department of Chemistry, D.D.U. Gorakhpur University, Gorakhpur, U.P, India;3. Department of Chemistry, B. N College of Engineering & Technology, Lucknow, U.P, India;4. Faculty of Chemical Sciences, Shri Ramswaroop Memorial University, Barabanki, 225 003, U.P, India |
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Abstract: | The most crucial and demanding universal issue lies in the enrichment of sustainable drive technology. As traditional resource, petrochemical becomes increasingly scarce in the future; mankind must turn to renewable alternatives to yield liquefied fuels and valuable commodities through sustainable process. It has been reported that furan compounds serve as an excellent platform molecule derived from defatted rice bran. The current work aims at the synthesis of copper ferrite nano catalyst by microwave assisted solution incineration approach. The catalytic properties stood verified by X-ray diffraction, SEM, EDAX and BET techniques. The catalytic performance of the copper ferrite catalyst were reinforced through in-situ microwave assisted acetalization reaction of furfural with discrete solvents like methanol, ethanol, and 1-propanol at optimum reaction conditions for the preparation of wide range of commodity chemicals such as carboxylic acids, alkyl esters, di alkyl acetals, di ketones which are of commercial importance. The comparative study of relative yield of the products with different solvents is reported. The formation of the value-added products were confirmed by GC-MS, FT-IR technique. The catalysts from the reaction mixture are recovered by magnetic field. |
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Keywords: | Defatted rice bran Furfuraldehyde In-situ acetalization Value added chemicals |
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