| 异核稀土双亚砜配合物的合成、表征和荧光性质 |
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| 引用本文： | 张若桦,马宝清.异核稀土双亚砜配合物的合成、表征和荧光性质[J].中国稀土学报,1999,17(1):7-11. |
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| 作者姓名： | 张若桦 马宝清 |
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| 作者单位： | 南开大学化学系!天津，300071，南开大学化学系!天津，300071，南开大学化学系!天津，300071，南开大学化学系!天津，300071，南开大学化学系!天津，300071，南开大学物理系!天津，300071 |
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| 基金项目： | 北京大学稀土材料化学及应用国家重点实验室资助 |
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| 摘 要： | 合成得到一系列异核土双乙烷配合物和异核稀土双乙烷与１，１０－啡咯啉的配合物，通过元素分析，电感耦合等离子体法，电导，红外和紫外光谱对配合进行了表征，并研究了这些配合物的固体和溶液的荧光光谱。
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| 关 键 词： | 稀土 铕 异核配合物 双亚砜 荧光性质 配合物 |
Synthesis, Characterization and Luminescent Properties on Heteronuclear Rare Earth Complexes |
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| Zhang Ruohua, Ma Baoqing, Bu Xianhe, Lu Shouliang, Weng Wei, Hou Yanbing.Synthesis, Characterization and Luminescent Properties on Heteronuclear Rare Earth Complexes[J].Journal of the Chinese Rare Earth Society,1999,17(1):7-11. |
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| Authors: | Zhang Ruohua Ma Baoqing Bu Xianhe Lu Shouliang Weng Wei Hou Yanbing |
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| Abstract: | A series of heteronuclear RE complexes with his (p he n y lsulfi n yi ) e t hane, an d bet ero n "clearRE complexes with his(phenylstilfinyl)ethane and l, 10-phenanthroline were synthesized andcharacterized by elemental analysis, inductively coupled plasma determination, conductivitymeasurement, infrared spectra and ultraviolet speCtra. Luminescent spectra for the Eu and Tbcomplexes in the solid state and solution were also studied. These complexes have strong luminescence among which the luminescent intensities of the ternary complexes are stronger thanthat of the binary complexes. The luminescent intensities of E.3 in the series of heteronuclearcomplexes have the following order: Eu--Y complexes > Eu--Gd complexes > Eu-Tbcomplexes > Eu complexes > Eu-La complexes. |
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| Keywords: | Rare earths Europium Heteronuclear complex Bisulfoxide Luminescent property |
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