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Investigations into the parallel kinetic resolution of 2-phenylpropanoyl chloride using quasi-enantiomeric oxazolidinones |
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| Authors: | Sameer Chavda Elliot Coulbeck Gregory S Coumbarides Marco Dingjan Jason Eames Stephanos Ghilagaber Yonas Yohannes |
| Institution: | aDepartment of Chemistry, University of Hull, Cottingham Road, Kingston upon Hull HU6 7RX, UK bDepartment of Chemistry, Queen Mary, University of London, Mile End Road, London E1 4NS, UK |
| Abstract: | The resolution of 2-phenylpropanoyl chloride using an equimolar combination of quasi-enantiomeric oxazolidinones is discussed. The levels of diastereoselectivity were found to be dependent upon the structural nature of the metallated oxazolidinone, temperature and metal counter-ion. |
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