|
|||||
|
|
Extension of linear free energy relationships to multiple ionizations |
|
| Authors: | Neil Purdie Mason B Tomson |
| Institution: | (1) Department of Chemistry, Oklahoma State University, Stillwater, Oklahoma |
| Abstract: | The linear additivity of free energies of ionization of substituted acids relative to the unsubstituted parent acid is described in terms of the Hammett relationship and as the weighted sums of microscopic free energies for benzenetricarboxylic acids. |
| Keywords: | Linear free energy relationships ionization constants Hammett equation polycarboxylic acids |
| 本文献已被 SpringerLink 等数据库收录！ | |