Electronic structure of vanadium oxide. Neutral and charged species, VO0,+/- |
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Authors: | Miliordos Evangelos Mavridis Aristides |
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Institution: | Laboratory of Physical Chemistry, Department of Chemistry, National and Kapodistrian University of Athens, P.O. Box 64 004, 157 10 Zografou, Athens, Greece. |
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Abstract: | The diatomic molecule vanadium oxide, VO, and its charged species VO+ and VO- were studied by multireference and coupled cluster methods in conjunction with large basis sets. The investigation of 22 states and the construction of 21 full potential energy curves allowed for a detailed understanding of the electronic structure of these species. Our best binding energies for the ground states of VO (X4Sigma-), VO+ (X3Sigma-), and VO- (X3Sigma-) were De = 150, 138, and 143 kcal/mol, respectively, in harmony with the corresponding experimental values. For both species VO and VO+ and for all states studied, the bonding showed a strong ionic character conforming to the models V+O- and V2+O-. |
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