The gas-phase molecular structure of methyl formate,determined by electron diffraction |
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Authors: | Stephen Cradock David WH Rankin |
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Institution: | Department of Chemistry, University of Edinburgh, West Mains Road, Edinburgh EH9 3JJ Gt. Britain |
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Abstract: | The structure of methyl formate in the gas phase has been reinvestigated by electron diffraction. The results confirm that the molecular skeleton is cis-planar, with bond lengths and angles in close agreement with those found by microwave techniques. Principal parameters (ra) are: r(CO) 120.2(2) pm, r(C-O) 134.0(2), and 143.5(3) pm; ∠ (OC-O) 125.4(5)°, and ∠ (C-O-C) 115.9(5)°. |
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