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Antisymmetry and stability of water systems. II. Polyhedral clusters
Authors:M V Kirov
Institution:(1) Institute of the Earth Cryosphere, Siberian Division, Russian Academy of Sciences, Tyumen
Abstract:The generalized symmetry of proton configurations of water polyhedral clusters is studied. A change in the directions of all hydrogen bonds is used as the additional approximate operation of antisymmetry. The dependence of the energy of antisymmetric configurations on the cluster stabilization energy is found. It is concluded that the internal molecular asymmetry of water that is caused by the approximate character of antisymmetry of hydrogen bonding can be of fundamental scientific importance.
Keywords:antisymmetry  asymmetry  water  polyhedral cluster  residual entropy  isomorphism  chirality
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