Crystal structure and luminiscent properties of 2,2-difluoro-4-(9H-hluorene-2-YL)-6-methyl-1,3,2-dioxaborine |
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Authors: | B V Bukvetskii E V Fedorenko and A G Mirochnik |
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Institution: | (1) Institute of Chemistry, Far-Eastern Branch of the Russian Academy of Sciences, 159 prosp. 100-letiya Vladivostoka, 690022 Vladivostok, Russian Federation |
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Abstract: | The crystal structure of 2,2-difluoro-4-(9H-fluorene-2-yl)-6-methyl-1,3,2-dioxaborine (C13H9COCH × COCH3BF2) (1) is determined. The structural and spectral luminescent characteristics of 1 are compared to those of its electron analogue:
2,2-difluoro-4-(4-phenylphenyl)-6-methyl-1,3,2-dioxaborine (C6H5C6H4 × COCHCOCH3BF2). |
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