Crystal structure of copper(II) bis-hexafluoroacetylacetonate |
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Authors: | S A Gromilov I A Baidina P A Stabnikov G V Romanenko |
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Institution: | (1) A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk;(2) International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk |
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Abstract: | An X-ray diffraction investigation has performed for copper(II) bis-hexafluoroacetylacetonate (Bruker AXS P4 automatic diffractometer, MoK
radiation, t = –25°C). Crystal data for C10H2CuF12O4: a = 5.530(1) Å, b = 6.038(1) Å, c = 11.266(2) Å, = 95.948(3)°, = 101.743(3)°, = 92.298(3)°, space group; P1, V = 365.6(1) Å3, Z = 1, d
calc = 2.169 g/cm3. The square-planar environment of the copper atom (Cu-Oav 1.912 Å, O-Cu-Oav 93°) is completed to bipyramidal by two fluorine atoms of the neighboring molecules, Cu...F 2.71 Å and 2.75 Å.Original Russian Text Copyright © 2004 by S. A. Gromilov, I. A. Baidina, P. A. Stabnikov, and G. V. RomanenkoTranslated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 3, pp. 502–507, May–June 2004. |
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Keywords: | copper -diketonates" target="_blank">gif" alt="beta" align="MIDDLE" BORDER="0">-diketonates X-ray diffraction analysis crystal chemistry |
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