Recent advances in the boration and cyanation functionalization of alkenes and alkynes |
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Institution: | 1. School of Pharmacy, Jinan University, 855 Xingye Avenue East, Guangzhou 511436, China;2. College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012 China |
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Abstract: | Alkenyl boron-esters and acrylonitrile groups are key structural functional groups found in dyes, pesticides, fluorescent compounds, functional materials, and biologically active drugs. Considerable efforts have been devoted for the introduction of boron-esters and acrylonitrile groups by using alkenes and alkynes conversion routes for boronation, hydroboronation, dehydrogenative boronation, cyanation, hydrocyanation, alkylcyanation, cyanomethylation. These reported methodologies are very valuable for the industrial production of acrylonitriles and alkenyl boron esters. |
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Keywords: | Metal catalyst Boronation Hydroboronation Dehydroboronation Cyanation/Hydrocyanation Cyanomethylation Alkynes Alkenes |
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