| Abstract: | Abstract A spectrophotometric procedure is described for the simultaneous determination of osmium and ruthenium in the form of bromo complexes. It was found that a blue ruthenium-thiourea complex could be formed in 6.7 M HBr solutions while the osmium could be maintained as the hexabromoosmate complex. Absorption maxima were at 620 μ for the ruthenium complex and at 446 μ for the osmium complex. Molar absorptivities for the ruthenium complex were 2.47 × 103 at 620 μ and 763 at 446 μ. For the osmium complex molar absorptivities were 328 at 620 μ and 6.81 × 103 at 446 μ. The method is useable over the range of 5 to 30 ppm with an absolute error of = 1 ppm over the range. Other platinum metals interfere. |
