Constructing novel red-emitting Ba2Y0.8Eu0.2NbO6:Mn4+ phosphors for multi-type luminescent thermometers and high-security anti-counterfeiting films |
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Authors: | Y Hua T Wang W Xia JS Yu L Li |
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Institution: | 1. Department of Electronics and Information Convergence Engineering, Institute for Wearable Convergence Electronics, Kyung Hee University, Yongin-si, Gyeonggi-do 17104, Republic of Korea;2. School of Science, Chongqing University of Posts and Telecommunications, Chongqing 400065, PR China |
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Abstract: | To date, luminescent materials have been preferably used for non-contact optical thermometers. In this manner, novel red-emitting Ba2Y0.8Eu0.2NbO6:Mn4+ (BYEN:Mn4+) phosphors were designed for multi-type non-contact luminescent thermometers based on the dual-emission states and temperature-dependent lifetime (TDL) models. In the temperature range of 303–483 K, the sensing sensitivities based on the dual-emission states of (5D0→7F2, 2Eg→4A2g) and (5D0→7F1, 2Eg→4A2g) were estimated. Especially, the maximum absolute sensing sensitivity (Sa) was found to be about 0.1558 K-1 for the BYEN:0.007Mn4+ phosphor based on the 5D0→7F1 and 2Eg→4A2g positions. This phosphor also exhibited good relative sensing sensitivity (Sr) (0.0186 K-1) based on the 5D0→7F2 and 2Eg→4A2g states. Besides, the relative sensing sensitivities (SR) at 5D0→7F1 and 2Eg→4A2g transitions were estimated to be 0.0034 and 0.0194 K-1, respectively with the help of the TDL technique. In the light of these results, novel red-emitting Ba2Y0.8Eu0.2NbO6:Mn4+ phosphors are expected to be a potentially attractive candidate for applications in multi-type luminescent thermometers. Finally, a novel unique polydimethylsiloxane film exhibiting tricolor-luminescent emissions was introduced and further suggested for high-security anti-counterfeiting. |
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Keywords: | Phosphors Fluorescence intensity ratio Temperature-dependent lifetime Luminescence Sensing sensitivity Polydimethylsiloxane films |
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