Relative Responses of Noble Gases Using a Pulsed Discharge Helium Photoionization Detector:Theoretical Calculation and Experimental Determination |
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| Authors: | ZHANG Hai-tao WU Di ZHANG Li-xing |
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| Institution: | a Northwest Institute of Nuclear Technology, Xi'an 710024, P. R. China;
b State Key Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, Jilin University, Changchun 130023, P. R. China |
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| Abstract: | The relative response factors(RRFs) for noble gas(Ng) were determined on a pulsed discharge helium photoionization detector,Using ab initio method,the atomic orbitals of noble gas were calculated and used to determine the number of ionizable electrons on the basis of the continuous emission of He2,The molar responses of noble gases is well correlated with the number of ionizable electrons. |
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| Keywords: | Relative response Noble gas Pulsed discharge helium photoionization detector |
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