| Solvothermal Synthesis and Characterization of （ NH3 CH2 CH2 NH3） HgSnS4 with a Column Structure |
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| 作者姓名： | WANG Yan-yan~ BAIYIN Meng-he~ JI Shou-hua~ LIU Xiao-yang~ AN Yong-lin~ and NING Gui-ling~ . |
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| 作者单位： | WANG Yan-yan~ 1，BAIYIN Meng-he~ 1，JI Shou-hua~ 2，LIU Xiao-yang~ 3，AN Yong-lin~ 1 and NING Gui-ling~ 1 1. Department of Chemistry，2. Department of Materials，Dalian University of Technology，Dalian 116024，P. R. China; 3. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry，Jilin University，Changchun 130023，P. R. China |
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| 摘 要： | IntroductionSulfide-based open-framework materials are in-triguing compounds.They possess very diverse and in-teresting structures,and exhibit potential applicationsas a newgeneration of molecular sieves with the proper-ties of semiconductor materials1].…
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| 关 键 词： | 溶剂热分析 表征 孔结构 四硫代锡酸盐 晶体结构 |
| 文章编号： | 1005-9040（2006）-04-411-04 |
| 收稿时间： | 2005-07-07 |
Solvothermal Synthesis and Characterization of (NH3CH2CH2NH3)HgSnS4 with a Column Structure |
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| WANG Yan-yan ,BAIYIN Meng-he ,JI Shou-hua ,LIU Xiao-yang ,AN Yong-lin and NING Gui-ling ..Solvothermal Synthesis and Characterization of (NH3CH2CH2NH3)HgSnS4 with a Column Structure[J].Chemical Research in Chinese University,2006,22(4):411-414. |
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| Authors: | Yan-yan WANG Meng-he BAIYIN Shou-hua JI Xiao-yang LIU Yong-lin AN Gui-ling NING |
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| Institution: | aDepartment of Chemistry, Dalian University of Technology, Dalian 116024, P. R. China;bDepartment of Materials, Dalian University of Technology, Dalian 116024, P. R. China;cState Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China |
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| Abstract: | A compound (NH3CH2CH2NH3)HgSnS4 with a column structure was synthesized solvothermally and characterized by X-ray single-crystal diffraction. This compound crystallizes in the monoclinic space group C2/c with a=1.3863(6) nm, b=0.6640(3) nm, c=2.3198(10) nm, β=106.168(7)° and Z=8. It consists of anionic columns of HgSnS4]2-∞ that are interrupted by cationic columns of EnH2]2 . Its thermal and optical properties were studied. |
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| Keywords: | Solvothermal synthesis Quaternary thiostannate Crystal structure |
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