| Ce（SO4）2-mediated Oxidative Coupling of Primary Aromatic Amines in Water |
| |
| 作者单位： | Key Laboratory of Bioorganic Phosphorus Chemistry ＆ Chemical Biology, Ministry of Education, Department of Chemistry, Tsinghua University, Beo＇ing 100084, P. R. China |
| |
| 基金项目： | Supported by the National Natural Science Foundation of China(No.20572058) |
| |
| 摘 要： |
|
| 关 键 词： | 氧化偶联 芳香胺 小学 介导 水 铈 二甲基苯胺 二乙基苯胺 |
Ce(SO_4)_2-mediated Oxidative Coupling of Primary Aromatic Amines in Water |
| |
| Authors: | LU Wen-chao XI Chan-juan Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology Ministry of Education |
| |
| Institution: | LU Wen-chao and XI Chan-juan Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology,Ministry of Education,Department of Chemistry,Tsinghua University,Beijing 100084,P. R. China |
| |
| Abstract: | The oxidative coupling of primary aromatic amines was investigated. Ce(SO4)2 can mediate the oxidative coupling of primary aromatic amines in water to dimers, trimers and/or tetramers, which depended on the substituents of primary aromatic amines. When 2,6-dimethylaniline or 2,6-diethylaniline was used as substrate, dimer, and tetramer were formed as major products. When 2,6-diisopropylaniline or 2,6-dihaloanilines was used as substrate, dimer, and trimer were formed. The mechanistic aspect was also investi... |
| |
| Keywords: | Primary aromatic amine Oxidative coupling Cerium sulfate |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
