| Synthesis, Electrochemistry, and Photophysics of a Novel Binuclear Polypyridyl Ru(Ⅱ) Complex with an 1,8-Adipoylamidobis(1,10-phenanthroline-5-yl) Ligand |
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| 作者姓名： | WANG Peng WANG Jun JING Xiao-yan WANG Xiang-ping ZHU Guo-yi |
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| 作者单位： | Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry,Chinese Academy of Sciences, Changchun 130022, P. R. China,Department of Chemical Engineering, Harbin Engineering University,Harbin 150001, P. R. China |
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| 基金项目： | the Ministry of Science and Technology of China，， |
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| 摘 要： | The present paper covers the syntheses of 1,8-adipoylamido-bis(1,10-phenanthroline-5-yl)(bphaa) and its binuclear complex {(bpy)2Ru]2(bphaa)}(PF6)4, where bpy is 2,2′-bipyridine. The two novel compounds were confirmed by means of elemental analysis, IR, LD-MS and 1H NMR, and 1H NMR spectra were completely assigned in virtue of 1H-1H COSY. The electrochemical behavior of the binuclear Ru(Ⅱ) complex was obtained using cyclic and square-wave voltammetry. Its photophysical property was investigated by electronic absorption, fluorescence excitation and emission spectra.
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| 关 键 词： | 1 8-Adipoylamido-bis(1 10-phenanthroline-5-yl) Cyclic voltammetry Square-wave voltammetry Electronic absorption Fluorescence |
Synthesis, Electrochemistry, and Photophysics of a Novel Binuclear Polypyridyl Ru(Ⅱ) Complex with an 1,8-Adipoylamidobis(1,10-phenanthroline-5-yl) Ligand |
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| WANG Peng,WANG Jun,JING Xiao-yan,WANG Xiang-ping,ZHU Guo-yi.Synthesis, Electrochemistry, and Photophysics of a Novel Binuclear Polypyridyl Ru(Ⅱ) Complex with an 1,8-Adipoylamidobis(1,10-phenanthroline-5-yl) Ligand[J].Chemical Research in Chinese University,2000,16(2):146-151. |
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| Authors: | WANG Peng WANG Jun JING Xiao-yan WANG Xiang-ping ZHU Guo-yi |
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| Abstract: | The present paper covers the syntheses of 1,8-adipoylamido-bis(1,10-phenanthroline-5-yl)(bphaa) and its binuclear complex {(bpy)2Ru]2(bphaa)}(PF6)4, where bpy is 2,2′-bipyridine. The two novel compounds were confirmed by means of elemental analysis, IR, LD-MS and 1H NMR, and 1H NMR spectra were completely assigned in virtue of 1H-1H COSY. The electrochemical behavior of the binuclear Ru(Ⅱ) complex was obtained using cyclic and square-wave voltammetry. Its photophysical property was investigated by electronic absorption, fluorescence excitation and emission spectra. |
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| Keywords: | Adipoylamido-bis(1 10-phenanthroline-5-yl) Cyclic voltammetry Square-wave voltammetry Electronic absorption Fluorescence |
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