Comparison Between Performances of PbO2 and F--doped PbO2 Anodes for Electrochemical Degradation of Aniline |
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Authors: | WANG Xuan HUANG Wei-min LI Hui-ting ZHANG Xue-na LU Hai-yan and LIN Hai-bo |
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Institution: | 1. College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Suzhou Nistar Chemical Technology Co. Ltd., Suzhou 215123, P. R. China |
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Abstract: | The paper deals with the influence of anode material on the efficiency of degradation for organic pollutants in water system.The electrochemical performance of fluorine ion doped lead dioxide(F--PbO2) electrode for the degradation of aniline was compared with that of undoped lead dioxide(PbO2) electrode by ultraviolet-visible(UV-Vis) spectroscopy,linear voltammetry and other analytical methods,such as the measurement by chemical oxygen demand analyzer,high performance liquid chromatography and scanning electron micrography.It was shown that both PbO2 electrode and F--PbO2 electrode could make aniline be mineralized completely and have the same degradation course,but F--PbO2 electrode has much higher electrocatalytic activity than undoped PbO2 electrode for the electrochemical degradation of aniline.The experimental results confirm that F--PbO2 electrode has much higher potential for oxygen evolution than undoped PbO2 electrode. |
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Keywords: | Lead dioxide electrode Electrochemical oxidation Degradation Aniline |
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