Oxidation of Propylene with Oxygen and Air in a Barrier Discharge in the Presence of Octane |
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Authors: | Sergey Kudryashov Andrey Ochered’ko Andrey Ryabov Galina Shchyogoleva |
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Institution: | (1) Institute of Petroleum Chemistry, Siberian Branch of the Russian Academy of Sciences, Tomsk, Russia |
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Abstract: | Oxidation of propylene with oxygen, air and a mixture of nitrogen–oxygen in a barrier discharge is investigated. The selectivity
towards formation of propylene oxide in pure oxygen is shown to be as high as 45 wt% and the propylene conversion ratio is
found to be 12.9 wt%. In the oxidation with air, the propylene oxide selectivity is 23 wt%, while the conversion is 7.5 wt%.
The values of propylene conversion and selectivity towards formation of propylene oxide in a barrier discharge are consistent
with those obtained by the thermocatalytic methods for production of propylene oxide. |
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