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1-(5-萘酚-7-磺酸)-3-[4-(苯基偶氮)苯基]-三氮烯的合成及与阳离子表面活性剂的显色反应
引用本文:冯泳兰,邝代治,许金生,王剑秋,刘梦琴.1-(5-萘酚-7-磺酸)-3-[4-(苯基偶氮)苯基]-三氮烯的合成及与阳离子表面活性剂的显色反应[J].分析化学,2002,30(2):189-191.
作者姓名:冯泳兰  邝代治  许金生  王剑秋  刘梦琴
作者单位:衡阳师范学院化学系,衡阳,421008
基金项目:湖南省教育厅资助课题(No.00C265)
摘    要:报道了1-(5-萘酚-7-磺酸)-3-4-(苯基偶氮)苯基]-三氮烯(NASAPAPT)的合成,研究了该试剂与阳离子表面活性剂溴化十二烷基二甲基苄铵(DDMBAB),溴化十六烷基三甲铵(CTMAB)、溴化十六烷基吡啶(CPB)、溴化十四烷基吡啶(TPB)显色反应的条件。测定了显色反应的灵敏度,符合比尔定律的范围。建立了光度法测定微量阳离子表面活性剂的新方法。

关 键 词:1-(5-萘酚-7-磺酸)-3-[4-(苯基偶氮)苯基]-三氮烯  阳离子表面活性剂  显色反应  合成  测定  分析  光度法

Colour Reactions of Reagent 1-(5-Naphthol-7-sulfonic acid)-3-(4-phenylazophenyl)triazene with Cationic Surfactants
Feng Yonglan,Kuang Daizhi,Xu Jinsheng,Wang Jianqiu,Liu Mengqin.Colour Reactions of Reagent 1-(5-Naphthol-7-sulfonic acid)-3-(4-phenylazophenyl)triazene with Cationic Surfactants[J].Chinese Journal of Analytical Chemistry,2002,30(2):189-191.
Authors:Feng Yonglan  Kuang Daizhi  Xu Jinsheng  Wang Jianqiu  Liu Mengqin
Abstract:The synthesis of new reagent 1-( 5-naphthol-7-sulfonic acid )-3-( 4-phenvlazophenyl) triazene(NASAPAPT) and the condition of its colour reaction with dodecyldimethylbenzylammonium bromide(DDMBAB), cetyltrimethylammonium, bromide(CTMAB), cetylpyridinium bromide(CPB) and tetradecylpyridinium bromide(TPB) were studied. The range for the determination and their apparent molar absorptivities were determined. The method for the spectropotometric determination of trace cationic surfactants(CTMAB, DDMBAB, CPB and TPB) was established.
Keywords:Naphthol-7-sulfonic acid)-3-( 4-phenylazophenvl) triazene  cationic surfactants  colour reaction
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