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杯芳烃衍生物在分析化学中的应用
引用本文:林琳,吴采樱.杯芳烃衍生物在分析化学中的应用[J].分析化学,1997,25(7):850-856.
作者姓名:林琳  吴采樱
作者单位:武汉大学化学系!武汉430072
摘    要:杯芳烃衍生物是以杯芳烃为“分子平台”,经过不同的衍生化而得。根据杯芳烃的空腔大小,构象及其衍生官能团与客体分子间的适应程度,杯芳烃衍生物可实现对金属离子及有机分子的选择性识别。本文介绍了芳烃衍生物在分析化学领域,包括萃取分离,液膜分离,色谱分析及光分析中的应用情况。

关 键 词:杯芳烃衍生物  分析化学  特性  主体分子  模拟酶

Applications of Calixarene Derivatives in Analytical Chemistry
Lin Lin,Wu Caiying..Applications of Calixarene Derivatives in Analytical Chemistry[J].Chinese Journal of Analytical Chemistry,1997,25(7):850-856.
Authors:Lin Lin  Wu Caiying
Abstract:Calixarene derivatives, possessing a high degree of preorganization of the cavity size, conformation and functional groups, are ideal hosts suited to the purpose of complexa- tion and inclusion guests. They can receive either ions or neutral molecules and exhibit a high selectivity and complexing ability as compared with crown ethers. This paper gives a re- view of their applications in analytical chemisty with 52 references. The described examples concern extractant in extraction separation, carrier in liquid membrane separation and in ion selective electrode, additive in capillary electrophoresis, stationary phase in chromatography and chromoionophore or fluorionophore in optical analysis.
Keywords:Calixarene derivative  analytical character  review
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