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| 超高效液相色谱-质谱法检测土壤中的羟基化多溴联苯醚 | |
| 引用本文： | 徐能斌,钱飞中,冯加永,汪晟乐,洪正昉,徐立红,陈钟佺.超高效液相色谱-质谱法检测土壤中的羟基化多溴联苯醚[J].分析化学,2015(2):251-256. |
| 作者姓名： | 徐能斌 钱飞中 冯加永 汪晟乐 洪正昉 徐立红 陈钟佺 |
| 作者单位： | 1. 宁波市环境监测中心,宁波,315012 2. 浙江省环境监测中心,杭州,310012 3. 绍兴市环境监测中心,绍兴,312000 |
| 基金项目： | 国家高技术研究发展计划，环保部科研公益性行业专项，宁波市自然科学基金(No.2011A610087)资助This work was supported by the National High Tech Research and Development Program，the Special Fund for Envi-ronmental Scientific Research in the Public Interest，the Ningbo City Natural Science Foundation |
| 摘 要： | 建立了土壤中8种羟基化多溴联苯醚(Hydroxylated polybrominated diphenyl ethers,OH-PBDEs)的Qu ECh ERS-超高效液相色谱串联质谱(UPLC-MS/MS)分析方法。样品前处理采用Qu ECh ERS方法,土壤样品用水浸润之后,以甲酸和乙腈提取目标物,C18填料和正丙基乙二胺(PSA)净化,C18色谱柱分离,乙腈和水梯度洗脱,多反应监测负离子模式扫描。在最佳实验条件下,8种目标物在9 min内分离良好,并在2~200μg/L范围内线性良好,相关系数范围在0.9936~0.9990,检出限范围为0.23~1.21 ng/g。在5.0和50 ng/g 2个浓度水平6次平行加标实验中,8种OH-PBDEs平均回收率为73.2%~117.7%,相对标准偏差为5.6%~19.7%。本方法操作简便,灵敏度高,适用于大批量样品的快速分析。 |
| 关 键 词： | 羟基化多溴联苯醚 土壤 超高效液相色谱-质谱法 |
Determination of Hydroxylated Polybrominated Diphenyl Ethers in Soils by QuEChERS-Ultra Performance Liquid Chromatography-Tandem Mass Spectrometry |
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| XU Neng-Bin,QIAN Fei-zhong,FENG Jia-Yong,WANG Sheng-Le,HONG Zheng-Fang,XU Li-Hong,CHEN Zhong-Quan.Determination of Hydroxylated Polybrominated Diphenyl Ethers in Soils by QuEChERS-Ultra Performance Liquid Chromatography-Tandem Mass Spectrometry[J].Chinese Journal of Analytical Chemistry,2015(2):251-256. | |
| Authors: | XU Neng-Bin QIAN Fei-zhong FENG Jia-Yong WANG Sheng-Le HONG Zheng-Fang XU Li-Hong CHEN Zhong-Quan |
| Institution: | XU Neng-Bin;QIAN Fei-zhong;FENG Jia-Yong;WANG Sheng-Le;HONG Zheng-Fang;XU Li-Hong;CHEN Zhong-Quan;Ningbo Environmental Monitoring Center;Zhejiang Environmental Monitoring Center;Shaoxing Environmental Monitoring Center; |
| Abstract: | |
| Keywords: | Hydroxylated polybrominated diphenyl ethers Soils Ultra performance liquid chromatography-tandem mass spectrometry |
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