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| 碳酸二甲酯法制备1,5-萘二氨基甲酸甲酯中间产物的结构表征 | |
| 引用本文： | 肖福魁,张德胜,董庆年,魏伟,朴贞顺,徐宏,赵宁,孙予罕.碳酸二甲酯法制备1,5-萘二氨基甲酸甲酯中间产物的结构表征[J].分析化学,2006,34(3):415-417. |
| 作者姓名： | 肖福魁 张德胜 董庆年 魏伟 朴贞顺 徐宏 赵宁 孙予罕 |
| 作者单位： | 1. 中国科学院山西煤炭化学研究所煤转化国家重点实验室,太原,030001;中国科学院研究生院,北京,100039;中国石油吉林石化公司研究院,吉林,132021 2. 中国石油吉林石化公司研究院,吉林,132021 3. 中国科学院山西煤炭化学研究所煤转化国家重点实验室,太原,030001 |
| 摘 要： | 研究发现,由碳酸二甲酯与1,5-萘二胺合成1,5-萘二氨基甲酸甲酯的反应是一个经过中间产物的串联反应。关于这个中间产物,在目前现有的各种文献中未见报道。本文利用萃取、结晶等分离手段提纯出了该中间产物,并通过质谱、元素分析、红外光谱以及核磁共振谱等分析方法对其组成和结构进行了测定,结果表明该中间产物的分子量为216,组成为C12H12N2O2,结构为5-氨基-萘基-1-氨基甲酸甲酯。 |
| 关 键 词： | 5-氨基-萘基-1-氨基甲酸甲酯 结构表征 质谱 红外光谱 核磁共振谱 |
| 收稿时间： | 05 19 2005 12:00AM |
| 修稿时间： | 2005-05-192005-08-08 |
The Characterization of the Intermediate Produced in the Synthesis of 1, 5-Naphthalene Dicarbamate by Dimethylcarbonate Method |
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| Xiao Fukui,Zhang Desheng,Dong Qingnian,Wei Wei,Piao Zhenshun,Xu Hong,Zhao Ning,Sun Yuban.The Characterization of the Intermediate Produced in the Synthesis of 1, 5-Naphthalene Dicarbamate by Dimethylcarbonate Method[J].Chinese Journal of Analytical Chemistry,2006,34(3):415-417. | |
| Authors: | Xiao Fukui Zhang Desheng Dong Qingnian Wei Wei Piao Zhenshun Xu Hong Zhao Ning Sun Yuban |
| Institution: | 1.State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001;2.Graduate School of Chinese Academy of Sciences, Beijing 100039;3.Research institute of Jilin Petrochemical Company of Petrochina , Jilin 132021 |
| Abstract: | It was found that the reaction of 1, 5-naphthalene diamine (NDA) with dimethylcarbonate (DMC) to produce 1, 5-naphthalene dicarbamate was a series reaction through an intermediate. The intermediate was purified through extraction and crystallization and characterized by mass spectra, element analysis, Fourier transform infrared spectra and ~1H nuclear magnetic resonance spectroscopy, the result indicats that the intermediate of the reaction is 5-amino-naphthalene-1-carbamate (ANC) with a molecular weight of 216 and a composing of C_ 12 H_ 12 N_2O_2. |
| Keywords: | 5-Amino-naphthalene-1-carbamate structure characterization mass spectrometry Fourier transform infrared nuclear magnetic resonance |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |