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铽—钆—均苯四甲酸体系的共发光效应及其分析应用
引用本文:马文元,杨景和.铽—钆—均苯四甲酸体系的共发光效应及其分析应用[J].分析化学,1995,23(2):183-186.
作者姓名:马文元  杨景和
作者单位:山东大学化学系 济南250100
基金项目:国家自然科学基金资助项目
摘    要:本提出了以均苯四甲酸为配体的铽的荧光测定法,试验表明:在pH=6.0-9.0的缓冲溶液中,钆离子能明显增强Tb^3+-均苯四甲酸二元体系的荧光强度。该体系已用于痕量铽的测定,其检出限为4×10^-9mol/L。

关 键 词:    苯四甲酸  发光效应  荧光测定  稀土

Columinescence Effect of Terbium-Gadolinium-Pyromellitic Acid System and Its Analytical Application
Ma Wenyuan,Yang Jinghe,Ge Hongmei.Columinescence Effect of Terbium-Gadolinium-Pyromellitic Acid System and Its Analytical Application[J].Chinese Journal of Analytical Chemistry,1995,23(2):183-186.
Authors:Ma Wenyuan  Yang Jinghe  Ge Hongmei
Abstract:The fluorimetric determination of terbium using pyromellitic acid as the ligand is put forward. The experimental result showed that gadolinium ion could distinctly enhance the fluorescence intensity of the Tb-pyromellitic acid binary system in the buffer solution at pH 6. 0-9. 0. This system has been applied to the determination of trace terbium. The detection limit of terbium was 4*10-9 mol/L.
Keywords:Terbium  cadolinium  pyromellitic acid  columinescence effect  fluorimetry
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