| 苯酚和草酸二甲酯酯交换合成碳酸二苯酯反应产物的气相色谱-质谱分析 |
| |
| 引用本文： | 王胜平,李振花,马新宾,许根慧.苯酚和草酸二甲酯酯交换合成碳酸二苯酯反应产物的气相色谱-质谱分析[J].分析化学,2002,30(7):829-832. |
| |
| 作者姓名： | 王胜平 李振花 马新宾 许根慧 |
| |
| 作者单位： | 天津大学化工学院一碳化学与化工国家重点实验室,天津,300072 |
| |
| 基金项目： | 高等学校骨干教师资助计划，云南省省院省校合作项目资助课题 (No .0 0YT0 3) |
| |
| 摘 要： | 采用气相色谱-质谱联用、程序升温方法对苯酚和草酸二甲酯酯交换合成碳酸二苯酯反应产物进行了分析。实现了对钛酸四丁酯催化苯酚和草酸二甲酯二甲酯酯交换合成草酸二苯酯反应的主产物草酸二苯酯、中间产物甲基苯基草酸酯、副产物丁基苯基草酸酯、2-甲基丁醛、正丁醚及草酸二苯酯脱羰基生成碳酸二苯酯反应产物的定性，验证了苯酚和草酸二甲酯酯交换合成碳酸二苯酯反应分三步进行的反应模式。
|
| 关 键 词： | 苯酚 草酸二甲酯 酯交换 合成 碳酸二苯酯 反应产物 气相色谱－质谱 分析 |
Analysis of Synthesized Products from the Transesterification of Phenol with Dimethyl Oxalate by Gas Chromatography-Mass Spectrometry |
| |
| Wang Shengping,Li Zhenhua,Ma Xinbin ,Xu Genhui.Analysis of Synthesized Products from the Transesterification of Phenol with Dimethyl Oxalate by Gas Chromatography-Mass Spectrometry[J].Chinese Journal of Analytical Chemistry,2002,30(7):829-832. |
| |
| Authors: | Wang Shengping Li Zhenhua Ma Xinbin Xu Genhui |
| |
| Institution: | Wang Shengping,Li Zhenhua,Ma Xinbin *,Xu Genhui |
| |
| Abstract: | The synthesized products from the transesterification of phenol with dimethyl oxalate were analysed by combined means of programmed temperature-capillary gas chromatography-mass spectrometry. Diphenyl carbonate (DPC), diphenyl oxalate, methyl phenyl oxalate, butyl phenyl oxalate, 2-methyl butanal, n-butyl ether, dimethyl oxalate, phenol were separated and qualitatively analysed respectively. The results proved that the production of DPC from the transesterification of phenol with dimethyl oxalate followed 3-step reaction module. |
| |
| Keywords: | Diphenyl carbonate diphenyl oxalate methyl phenyl oxalate gas chromatography-mass spectrometry |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
