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六氟磷酸二(2,2'-联吡啶)·(4,4'-二甲基-2,2'-联吡啶) 合钌(Ⅱ)的二维核磁共振谱分析
引用本文:王鹏,袁艺,张密林,朱果逸.六氟磷酸二(2,2''''-联吡啶)·(4,4''''-二甲基-2,2''''-联吡啶) 合钌(Ⅱ)的二维核磁共振谱分析[J].分析化学,1999,27(6):648-652.
作者姓名:王鹏  袁艺  张密林  朱果逸
作者单位:1. 中国科学院长春应用化学研究所电分析化学开放研究实验室,长春,130022
2. 哈尔滨工程大学化学工程系,哈尔滨,150001
基金项目:国家科技攻关项目;96-A23-03-01;
摘    要:用一维NMR方法研究了电化学发光物质六氟磷酸二(2,2'-联吡啶)·(4,4'-二甲基-2,2'-联吡啶)合钌(Ⅱ)的立体结构,借助二维1H-1H COSY和1H-13C COSY实验技术对其氢谱和碳谱进行了完全的归属,并给出了其氢谱和碳谱的化学位移值.

关 键 词:六氟磷酸二(2  2'-联吡啶)·(4  4'-二甲基-2  2'-联吡啶)合钌(Ⅱ)  氢谱  碳谱  二维核磁共振谱
修稿时间:1998年9月2日

Analysis of 2D-Nuclear Magnetic Resonance for Ru ( 2,2'-bipyridine ) 2 ( 4,4'-dimethyl-2,2'-bipyridine ) ( PF6 ) 2
Wang Peng,Yuan Yi,Zhang Milin,Zhu Guoyi.Analysis of 2D-Nuclear Magnetic Resonance for Ru ( 2,2''''-bipyridine ) 2 ( 4,4''''-dimethyl-2,2''''-bipyridine ) ( PF6 ) 2[J].Chinese Journal of Analytical Chemistry,1999,27(6):648-652.
Authors:Wang Peng  Yuan Yi  Zhang Milin  Zhu Guoyi
Abstract:The 1H and 13C NMR spectra are reported for Ru(2, 2'-bipyridine)2 (4,4'-dimethyl-2,2'-bipyridine)(PF6)2 that may be used as electrochemiluminescent species. Because of the effect of Ru atom on ligands and complex steric configuration, it is difficult to attribute the spectra of the title molecular. By using 2D 1H-1H COSY and 1H-13C COSY methods, the proton and carbon-13 spectra are assigned completely. This also provides a basis for NMR characterization of the similar new compounds.
Keywords:Ru(2  2'-bipyridine)2 (4  4'-dimethyl-2  2'-bipyridine) ( PF6 )  two dimensional nuclear magnetic resonance
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