| 基于纳米SnO2材料的二维纳米催化发光传感器研制及其测定甲基叔丁基醚的应用 |
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| 引用本文： | 刘名扬,周硼,王宏伟,姚家彪,赵景红.基于纳米SnO2材料的二维纳米催化发光传感器研制及其测定甲基叔丁基醚的应用[J].分析化学,2011(9):1406-1411. |
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| 作者姓名： | 刘名扬 周硼 王宏伟 姚家彪 赵景红 |
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| 作者单位： | 辽宁出入境检验检疫局技术中心;大连交通大学环境与化工学院;大连理工大学化工学院; |
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| 基金项目： | 国家质检总局科研项目(Nos.2010IK025,2011IK034)资助 |
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| 摘 要： | 以碳纳米管(CNT)为模板,采用液相沉积法可控合成了SnO2-CNT复合纳米材料、SnO2纳米棒两种形貌的SnO2纳米材料,研究了它们对甲醇、MTBE催化发光的影响.通过考察两种不同形貌SnO2纳米材料的结构、比表面积与其催化发光的关系,建立了一种二维纳米催化发光传感器,并测定了MTBE产品的纯度和其中的甲醇含量,甲醇...
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| 关 键 词： | 可控合成 SnO2纳米材料 催化发光 二维传感器 甲基叔丁基醚 |
Two-Dimensional Cataluminescence Sensor Based on Nano-SnO_2 Materials for Determination of Methyl Tert-Butyl Ether |
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| LIU Ming-Yang,ZHOU Peng,WANG Hong-Wei,YAO Jia-Biao,ZHAO Jing-Hong.Two-Dimensional Cataluminescence Sensor Based on Nano-SnO_2 Materials for Determination of Methyl Tert-Butyl Ether[J].Chinese Journal of Analytical Chemistry,2011(9):1406-1411. |
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| Authors: | LIU Ming-Yang ZHOU Peng WANG Hong-Wei YAO Jia-Biao ZHAO Jing-Hong |
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| Institution: | LIU Ming-Yang1,2,ZHOU Peng3,WANG Hong-Wei1,YAO Jia-Biao1,ZHAO Jing-Hong1 1(Centre of Technique,Liaoning Entry-Exit Inspection and Quarantine Bureau,Dalian 116001) 2(College of Environment and Chemical Engineering,Dalian Jiaotong University,Dalian 116028) 3(College of Chemical Engineering,Dalian University of Technology,Dalian 116024) |
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| Abstract: | Two kinds of morphologies Nano-SnO2 materials,SnO2-CNT nanocomposites and nanorods,were controllably synthesized by liquid deposition method using CNT as a template.Cataluminescence(catalytic chemiluminescence,CTL) characteristic of methyl tert-butyl ether(MTBE) and methanol catalyzed on nanosized SnO2 with two kinds of morphologies was studied.BET surface area of the SnO2 nanomaterial was very important for the CTL.The relationship between two kinds of morphologies nano-SnO2 materials and CTL of MTBE and m... |
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| Keywords: | Controlled synthesis Nano-SnO2 materials Cataluminescence Two-dimensional sensor Methyl tert-butyl ether |
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