| 毛细管气相色谱,色谱—质谱联用测定金刚烷及其异构体 |
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| 引用本文： | 邱立勤,米镇涛.毛细管气相色谱,色谱—质谱联用测定金刚烷及其异构体[J].分析化学,1996,24(3):337-340. |
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| 作者姓名： | 邱立勤 米镇涛 |
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| 作者单位： | 天津大学天津石油化工技术开发中心!天津300072 |
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| 摘 要： | 本文给出了金刚烷及其异构体合物系毛细管气相色谱及色谱－质谱联用分析方法，色谱柱为ＣＢＰＩ键合石英毛细管、氢火焰检则器。列出了标准曲线和检测条件，回收率为９８．３％－１０１．２％，相对标准偏差〈４．０％，本方法定量分析快速、简便、准确。
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| 关 键 词： | 金刚烷 气相色谱 四氢双环戊二烯 色谱 质谱 |
Determination of Adamantane and Its Isomers by Capillary Gas Chromatography and Chromatography-Mass Spectrometry |
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| Qiu Liqin, Mi Zhentao, Zhang Xiangwen.Determination of Adamantane and Its Isomers by Capillary Gas Chromatography and Chromatography-Mass Spectrometry[J].Chinese Journal of Analytical Chemistry,1996,24(3):337-340. |
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| Authors: | Qiu Liqin Mi Zhentao Zhang Xiangwen |
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| Abstract: | This paper describes a capillary GC and GC-MS analytical method for the synthet ic adamantane and its isomers. The procedure involves the use of a fused silica column filled with bonded CBP1 stationary phase and FID detector. Standard curves and detection condi tions are given. The recoveries are 98. 3%~ 101. 2%. The RSD is less than 4. 0%. This quantitative analysis is fast, simple and accurate. |
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| Keywords: | Adamantane capillary gas chromatography tetrahydrodicyclopentadiene gas chromatography-mass spectrometry |
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