| [N_2O_2]型镍基配合物在中性水溶液中产氢性能的研究 |
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| 引用本文： | 刘思,辛芝娟,雷又嘉,王红艳.[N_2O_2]型镍基配合物在中性水溶液中产氢性能的研究[J].影像科学与光化学,2017,35(5). |
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| 作者姓名： | 刘思 辛芝娟 雷又嘉 王红艳 |
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| 作者单位： | 陕西师范大学化学化工学院,陕西西安,710119 |
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| 摘 要： | 通过简单易行的曼尼希(Mannich)反应,合成了一种N_2O_2]型配体,在少量三乙胺存在条件下,成功实现了与高氯酸镍配位,得到了镍金属配合物。通过核磁共振氢谱、高分辨质谱等手段对配体和配合物进行了表征。该化合物在水中具有一定的溶解度,并在中性磷酸缓冲溶液中显示出良好的电化学催化产氢活性。
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| 关 键 词： | 镍配合物 曼尼希(Mannich)反应 电催化 产氢 |
Nickle Complex with [N2O2]-type Ligand for Electrochemical Hydrogen Production in Neutral Aqueous Solution |
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| LIU Si,XIN Zhijuan,LEI Youjia,WANG Hongyan.Nickle Complex with [N2O2]-type Ligand for Electrochemical Hydrogen Production in Neutral Aqueous Solution[J].Imaging Science and Photochemistry,2017,35(5). |
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| Authors: | LIU Si XIN Zhijuan LEI Youjia WANG Hongyan |
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| Abstract: | Based on easy and accessible Mannich reaction,we synthesized a N2O2]-type ligand which was successfully coordinated with Ni(ClO4)2 to afford a nickle complex NiL.The ligand and the NiL complex was characterized by 1HNMR and HRMS.Electrochemical study indicates that the NiL complex exhibits excellent hydrogen production activity in neutral phosphate buffer. |
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| Keywords: | nickel complex Mannich reaction electrocatalysis hydrogen production |
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