| 适宜于光聚合过程应用的荧光探针研究 |
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| 引用本文： | 李青山,梁艳,周丽丽,姜永才,张晓宏,吴世康.适宜于光聚合过程应用的荧光探针研究[J].影像科学与光化学,2003,21(6):412-420. |
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| 作者姓名： | 李青山 梁艳 周丽丽 姜永才 张晓宏 吴世康 |
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| 作者单位： | 1. 中国科学院, 理化技术研究所, 北京, 100101;2. 齐齐哈尔大学, 材料化学系, 齐齐哈尔, 161006 |
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| 基金项目： | 国家重点基础研究发展计划(973计划) |
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| 摘 要： | 研究了两种探针化合物在安息香醚引发烯类单体光聚合反应中的应用.发现在光聚合反应中,不同的探针化合物有着不同的光谱响应特征和溶致变色行为,显然,这对探针的灵敏度会带来影响.实验结果表明:探针化合物在光聚合反应中能否应用,其光照稳定性起着关键作用.本工作推荐了一种适宜在烯类单体光聚合反应中应用的探针化合物.
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| 关 键 词： | 荧光探针 光聚合 探针的光照稳定性 安息香及其衍生物 |
| 收稿时间： | 2003-06-20 |
A STUDY OF FLUORESCENCE PROBE USED SUITABLY IN THE PROCESS OF PHOTO-POLYMERIZATION |
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| LI Qing-shan,LIANG Yan,ZHOU Li-li,JIANG Yong-cai,ZHANG Xiao-hong,WU Shi-kang.A STUDY OF FLUORESCENCE PROBE USED SUITABLY IN THE PROCESS OF PHOTO-POLYMERIZATION[J].Imaging Science and Photochemistry,2003,21(6):412-420. |
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| Authors: | LI Qing-shan LIANG Yan ZHOU Li-li JIANG Yong-cai ZHANG Xiao-hong WU Shi-kang |
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| Institution: | 1. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101, P.R. China;2. Department of Material Chemistry, Qiqihaer University, Qiqihaer 161006, P.R. China |
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| Abstract: | The photo polymerization process of acrylate monomer initiated by benzoin ether has been studied by two kinds of fluorescence probe.It was found that the sensitivity of probe used in photo polymerization is concerned with the spectrum response and the solvato chromism behavior of probe.But the most important factor of probe in the process of photo polymerization is the property of photo stabilization.A fluorescence probe,which is suitable to use in the photo polymerization of acrylate monomer was recommended. |
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| Keywords: | fluorescence probe photo-polymerization photo-stability of probe benzoin and its derivatives |
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