| 酸碱调控的二茂铁咪唑电化学开关 |
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| 引用本文： | 谢楠,冯科,陈彬,张丽萍,佟振合,吴骊珠.酸碱调控的二茂铁咪唑电化学开关[J].影像科学与光化学,2011,29(1):45-53. |
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| 作者姓名： | 谢楠 冯科 陈彬 张丽萍 佟振合 吴骊珠 |
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| 作者单位： | 谢楠,XIE Nan(首都医科大学,化学生物学与药学院,北京,100069;中国科学院,理化技术研究所,光化学转换与功能材料重点实验室,北京100190);冯科,陈彬,张丽萍,佟振合,吴骊珠,FENG Ke,CHEN Bin,ZHANG Li-ping,TUNG Chen-ho,WU Li-zhu(中国科学院,理化技术研究所,光化学转换与功能材料重点实验室,北京100190) |
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| 基金项目： | 科技部国家重点基础研究计划发展项目，国家自然科学基金资助项目，北京市属市管高等学校人才强教计划，首都医科大学科研基金 |
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| 摘 要： | 本文设计合成了一系列具有共轭结构的二茂铁咪唑衍生物,它们在质子的作用下呈现显著的光谱、核磁及电化学响应.在中性(或碱性)环境中,其氧化还原波处于低电位,表现为分子"关"的状态;在酸性环境中,其氧化还原波处于高电位,表现为分子"开"的状态;通过酸碱的调控作用其氧化还原波可以在高、低电位之间可逆转换,能够作为一类新型的电化...
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| 关 键 词： | 二茂铁咪唑衍生物 电化学开关 酸碱调控 |
Acid/Base Controlled Electrochemical Switches Based on Ferrocenyl Imidazole Derivatives |
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| XIE Nan,FENG Ke,CHEN Bin,ZHANG Li-ping,TUNG Chen-ho,WU Li-zhu.Acid/Base Controlled Electrochemical Switches Based on Ferrocenyl Imidazole Derivatives[J].Imaging Science and Photochemistry,2011,29(1):45-53. |
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| Authors: | XIE Nan FENG Ke CHEN Bin ZHANG Li-ping TUNG Chen-ho WU Li-zhu |
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| Abstract: | A series of ferrocenyl imidazole derivatives were obtained via Radziszewski synthesis,which exhibit an intriguing spectroscopic and electrochemical response upon protonation.In neutral or basic solution,the compounds exhibit low redox potentials representing an OFF state;while in acidic solution,the protonized compounds exhibit high redox potentials representing an ON state;these processes are reversible and can be controlled via the adjustment of acid/base.All these features made these ferrocenyl molecules the promising electrochemical switches. |
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| Keywords: | ferrocenyl imidazole derivatives electrochemical switch acid/base control |
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