| 新型阳离子光引发剂[4-(2-羟基-3-丁氧基-1-丙氧基)苯基]苯碘鎓-六氟锑酸盐的合成及光敏性能的研究 |
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| 引用本文： | 黄强,熊万斌,姜厚友,刘晓亚,陈明清,杨成.新型阳离子光引发剂[4-(2-羟基-3-丁氧基-1-丙氧基)苯基]苯碘鎓-六氟锑酸盐的合成及光敏性能的研究[J].影像科学与光化学,2006,24(1):61-66. |
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| 作者姓名： | 黄强 熊万斌 姜厚友 刘晓亚 陈明清 杨成 |
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| 作者单位： | 江南大学, 化学与材料工程学院, 江苏, 无锡, 214036 |
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| 摘 要： | 以丁基缩水甘油醚和苯酚为起始原料,进行开环缩合反应制得1-丁氧基-3-苯氧基丙-2-醇.再与羟基对甲苯磺酰氧基苯反应得到4-(2-羟基-3-丁氧基 -1-丙氧基)]二苯碘鎓-六氟锑酸盐(简称BPI·SbF6),产率达79%.用1HNMR、UV、IR和元素分析对其结构进行了分析.初步研究了以BPI·SbF6为阳离子光引发剂的脂肪族环氧(CY179)感光体系的感光特性,结果表明CY179/BPI·SbF6感光体系有一定的后固化活性.
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| 关 键 词： | 阳离子光引发剂 碘鎓盐 光敏性 后固化活性 |
| 收稿时间： | 2005-08-30 |
Synthesis and Photosensitive of a Novel Cationic Photoinitiator [4-(2-Hydroxy-3-Butoxy-1-Propoxy)Phenyl] Phenyliodonium Hexafluoroantimonate |
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| HUANG Qiang,XIONG Wan-bing,JIANG Hou-you,LIU Xiao-ya,CHEN Ming-qing,YANG Cheng.Synthesis and Photosensitive of a Novel Cationic Photoinitiator [4-(2-Hydroxy-3-Butoxy-1-Propoxy)Phenyl] Phenyliodonium Hexafluoroantimonate[J].Imaging Science and Photochemistry,2006,24(1):61-66. |
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| Authors: | HUANG Qiang XIONG Wan-bing JIANG Hou-you LIU Xiao-ya CHEN Ming-qing YANG Cheng |
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| Institution: | School of Chemical and Material Engineering, Southern Yangtze University, Wuxi 214036, Jiangsu, P.R. China |
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| Abstract: | 4-(2-hydroxy-3-butoxy-1-propoxy)phenyl]phenyliodonium hexafluoroantimonate (BPI·SbF6) was prepared by the reaction of 2-propanol,1-butoxy-3-phenoxy with hydroxy(tosyloxy)io-do]benzene in approximately 79% yield. The later product BPI·SbF6 was identified by infrared spectrum, UV spectrum, 1HNMR spectrum and element analysis. The characteristic curves of pho-topolymerization system CY179/BPI·SbF6 with different concentration of initiator BPI·SbF6 and the characteristic post-curves of photopolymerization system CY179/BPI·SbF6 with different UV curing time were studied. |
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| Keywords: | cationic photoinitiator iodonium salt photosensitive post-curing |
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