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Photoinduced variations in the size of nanoparticles of CdS in colloidal solutions
Authors:V V Shvalagin  A E Raevskaya  A L Stroyuk  S Ya Kuchmii
Institution:(1) L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv, 03028, Ukraine
Abstract:The possibility of decreasing the size of colloidal nanoparticles of CdS in the oxidative photocorrosion reaction in the presence of methylviologen and of increasing their size during photocatalytic reduction of sulfur in ethanol in the presence of cadmium acetate. A dependence of the quantum yield of the latter reaction on the initial size of CdS nanoparticles was observed, which was interpreted as a result of quantum size effects. __________ Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 43, No. 3, pp. 170–175, May–June, 2007.
Keywords:nanoparticles of CdS  photocatalysis  photocorrosion  photochemical synthesis
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