Synthesis and thermal reactions of N-(2,3-epoxypropyl)diphenylamine |
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Authors: | B Barvainiene A Stanisauskaite V Getautis |
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Institution: | (1) Department of Organic Chemistry, Kaunas University of Technology, Kaunas, LT-50270, Lithuania;(2) Faculty of Technology, Kaunas College, Kaunas, LT-50468 |
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Abstract: | The synthesis of N-(2,3-epoxypropyl)diphenylamine is reported. It was found that thermal opening of the oxirane ring of N-(2,3-epoxypropyl)diphenylamine
occurred both at the secondary and the tertiary carbon atoms but the basic reaction product is 3-hydroxy-1-phenyl-1,2,3,4-tetrahydroquinoline.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 852–855, June, 2007. |
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Keywords: | 3-hydroxymethyl-1-phenylindoline 3-hydroxy-1-phenyl-1 2 3 4-tetrahydroquinoline N-(2 3-epoxypropyl)diphenylamine cyclization |
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