A new method for the synthesis of 5-bromo(aryl)methylene-substituted hydantoins |
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Authors: | R L Antipin E K Beloglazkina A G Magouga A N Chernysheva N V Zyk |
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Institution: | (1) M. V. Lomonosov Moscow State University, Moscow, 119992, Russia |
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Abstract: | It has been shown that bromination of 5-aryl-5-benzylidene-3,5-dihydro-4H-2-methylthioimidazol-4-one in methylene chloride
at room temperature leads to the addition of bromine at the double bond, but the the reaction of 5-aryl-3,5-dihydro-4H-2-methylthio-5-(2-pyridylmethylene)imidazol-4-one
gave complex compound of the starting materials. After boiling both of the compounds obtained in ethanol the corresponding
5-bromo(aryl)methylene]imidazolidine-2,4-diones were obtained.
Dedicated to Academician B. A. Trofimov on his 70th jubilee.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, 1406–1408, September, 2008. |
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Keywords: | 5-aryl-3 5-dihydro-4H-2-methylthioimidazol-4-ones hydantoins imidazoline-2 4-diones bromination addition-elimination |
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