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| ATRP合成星型聚4-乙烯基二苯乙烯及性能研究 | |
| 引用本文： | 种国双,路建美,李娜君,陶永新.ATRP合成星型聚4-乙烯基二苯乙烯及性能研究[J].化学研究与应用,2008,20(9). |
| 作者姓名： | 种国双 路建美 李娜君 陶永新 |
| 作者单位： | 1. 江苏工业学院材料科学与工程系,江苏,常州,213164 2. 江苏工业学院材料科学与工程系,江苏,常州,213164;苏州大学化学化工学院,江苏,苏州,215123 3. 苏州大学化学化工学院,江苏,苏州,215123 |
| 基金项目： | 国家自然科学基金，江苏省高技术研究发展计划项目，江苏省常州市科技计划项目 |
| 摘 要： | 本文以2-溴异丁酸季戊四醇四酯(PT-Br)为引发剂,CuBr为催化剂,五甲基二亚乙基三胺(PMDETA)为配体,引发荧光单体4-乙烯基二苯乙烯(VS)进行原子转移自由基聚合,合成了星型荧光聚合物,且分子量分布较窄(1.37～1.50).通过与线性聚4-乙烯基二苯乙烯(line-PVS)的性能比较,发现星型聚4-乙烯基二苯乙烯的溶液粘度和玻璃化转变温度都相对较低.另外,还通过荧光光谱对星型聚合物的光学性能进行了表征. |
| 关 键 词： | 原子转移自由基聚合 星型聚4-乙烯基二苯乙烯 性能 |
Study on synthesis and properties of star PVS via atom transfer radical polymerization |
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| ZHONG Guo-shuang,LU Jian-mei,LI Na-jun,TAO Yong-xin.Study on synthesis and properties of star PVS via atom transfer radical polymerization[J].Chemical Research and Application,2008,20(9). | |
| Authors: | ZHONG Guo-shuang LU Jian-mei LI Na-jun TAO Yong-xin |
| Abstract: | Star-shape fluorescent poly(4-vinyls)stilbene(PVS) was synthesized by the Atom transfer radical polymerization(ATRP) with pentaerythritol tetrakis(2-bromoisobutyrate)(PT-Br) as initiator,CuX as catalyst,PMDETA as ligand and 4-vinylstilbene(VS) fluorescent monomer,respectively.The "living" radical polymerization of 4-vinylstilbene(VS) can be controlled effectively with the low PDI(1.37~1.50).The star PVS exhibited a lower viscosity and glass transition temperatures as compared to its linear counterpart.Moreover,the optical properties of the star-shaped PVS have been characterized by fluorescence. |
| Keywords: | ATRP star poly(4-vinyls)stilbene fluorescence |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |