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| 二茂铁配位高分子吸波材料的合成与性能表征 | |
| 引用本文： | 唐红梅,袁茂林,邓科,孙永贵,陈洪,郑春宁,林展如.二茂铁配位高分子吸波材料的合成与性能表征[J].化学研究与应用,2010,22(1). |
| 作者姓名： | 唐红梅 袁茂林 邓科 孙永贵 陈洪 郑春宁 林展如 |
| 作者单位： | 1. 宜宾学院化学化工系,四川,宜宾,644007;四川大学化学学院,四川,成都,610064 2. 四川大学化学学院,四川,成都,610064 3. 宜宾天原集团股份有限公司技术中心,四川,宜宾,644004 4. 四川师范大学化学与材料科学学院,四川,成都,610066 |
| 摘 要： | 本文以二茂铁为原料,经独特的分子设计,将导电的共轭基团引入二茂铁高分子化合物中,再使分子中共轭基团和金属原子M配位,合成既含"磁性"基元的金属原子离域结构,又有"导电"基元的茂环和共轭取代基组成的大共轭体系的新一类高分子化合物。研究结果表明这种新型的二茂铁高分子材料具有较好的吸波性能。 |
| 关 键 词： | 分子设计 二茂铁高分子 配位缩聚物 吸波性能 |
Synthesis and characterization of ferrocenyl coordination polymer served as absorbing-wave materials |
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| TANG Hong-mei,YUAN Mao-lin,DENG Ke,SUN Yong-gui,CHEN Hong,ZHENG Chun-ning,LIN Zhan-ru.Synthesis and characterization of ferrocenyl coordination polymer served as absorbing-wave materials[J].Chemical Research and Application,2010,22(1). | |
| Authors: | TANG Hong-mei YUAN Mao-lin DENG Ke SUN Yong-gui CHEN Hong ZHENG Chun-ning LIN Zhan-ru |
| Abstract: | In this paper, ferrocene was used as raw material, the conjugated group bearing conductive function was introduced into ferrocenyl polymeric compound by means of special molecular designs.Then the conjugated group in molecular coordinated with different metallic atom M(Fe、Cr、Mn).Therefore, a new polymeric compound containing both metallic atom with delocalization structure of "magnetic" group and the conjugated system consisted of cyclopentadienide ring and conjugated substituent of the "conductive" group was synthesized.Results showed that the new ferrocenyl polymeric had good absorbing-wave performance relatively. |
| Keywords: | molecular design ferrocenyl polymer coordination polycondensation absorbing-wave performance |
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