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基于金属有机骨架材料Tb-BTC显现潜指印的研究
引用本文:刘嘉扬,刘丽.基于金属有机骨架材料Tb-BTC显现潜指印的研究[J].化学研究与应用,2022,34(1):68-77.
作者姓名:刘嘉扬  刘丽
作者单位:中国刑事警察学院刑事科学技术学院,辽宁 沈阳 110854
基金项目:2020年度研究生创新能力提升项目(2020YCYB32)资助。
摘    要:为探究金属有机骨架材料在指印显现领域的应用,本研究采用预混合迅速滴显的方法,使金属有机骨架材料Tb-BTC直接络合在指印纹线上.使用该材料对渗透性客体中A4纸、黑色卡纸、牛皮纸;非渗透性客体中透明玻璃片、瓷砖上的皮脂指印进行显现,探究了不同配比、不同滴加顺序、不同显现时间的预混合溶液对不同类型、不同遗留时间、不同遗留物...

关 键 词:金属有机骨架材料  激发荧光  指印  显现

Research on the development of latent fingerprints based on metal-organic framework material Tb-BTC
LIU Jia-yang,LIU Li.Research on the development of latent fingerprints based on metal-organic framework material Tb-BTC[J].Chemical Research and Application,2022,34(1):68-77.
Authors:LIU Jia-yang  LIU Li
Institution:(Criminal Investigation Police University of China,Criminal Science and Technology College,Shenyang 110854,China)
Abstract:In order to explore the application of metal organic framework materials in the field of fingerprint development,this study adopts the method of pre-mixing and rapid dripping to make the metal organic framework material Tb-BTC directly complex on the ridge lines.Using this material to develop sebum-resulted fingerprints on A4 paper,black cardboard,kraft paper,transparent glass sheets and tiles in permeable objects and non-permeable objects;exploring the predictions of different proportions,different dropping orders,and different development times.The mixed solution shows the effect of latent fingerprints of different types,different retention times,and different quality of the leftovers.The results show that when the ratio of Tb3+ to BTC3- ions is 1∶2,when Tb3+ is added first and then BTC3-is added,it has a good effect on the appearance of sebum fingerprints on both permeable and non-permeable objects;the best development time of sebum-resulted fingerprints on A4 paper,Black cardboard,kraft paper,transparent glass sheet,ceramic tile objects are 90s,60s,60s,60s,90s;The Tb-BTC substance can effectively develop sebum-resulted fingerprints with a retention time of less than 5 days and different quality of the remaining material.The ridge lines are clear and smooth,and the contrast with the object background is high.Under the excitation of 254nm ultraviolet light,it releases bright and uniform green fluorescence.Therefore,it can be widely used in the development of sebum-resulted fingerprints on various objects to improve the efficiency of fingerprint development.
Keywords:metal organic framework materials  excited fluorescence  fingerprint  development
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