对环芳烷二氯化产物组成的GC—MS表征

对环芳烷(2,2]Paracyclophane,简称PCP）是指苯环对位桥联的化合物,PCP及其氯代PCP的重要用途是通过升华、裂解、聚合等步骤沉积于物体表面形成聚合膜,该聚合膜具有透湿和透气小、抗化学腐蚀和抗辐射等优良性能1,2].

Determination of the chlorinating reaction products of [2,2]-Paracyclophane by GC-MS

Gas chromatography with ion-trap mass spectrometric detector(GC-MS)was used to determine the chlorinating reaction products of 2,2]-paracyclophane(PCP).Results with mass chromatogram analysis indicates the chlorinating reaction products of PCP are chloro-2,2]-paracyclophane mixtures,and different compound has a few kinds of isomers respectively.Chloro-2,2]-paracyclophane mixture consists of one-chloro-2,2]-paracyclophane(one-chloro-PCP)with single structure,two-chloro-2,2]-paracyclophane(two-chloro-PCP)with five types of isomers,and three-chloro-2,2]-paracyclophane(three-chloro-PCP)with four types of isomers.In fact,there are three isomers with two Cl on two benzenes respectively and two isomers with two Cl on a benzene simultaneity in two-chloro-PCP compound,there are four isomers with a Cl on a benzene and two Cl on the other benzene in three-chloro-PCP compound.The two-chloro-PCP compound is determined to be the main component and the others are subsidiary substances from RIC of the chlorinating products of PCP.