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| 氢化诺卜醇及其烷基醚的合成与表征 | |
| 引用本文： | 赵玲华,肖转泉,陈金珠,王宗德,范国荣,陈尚钘.氢化诺卜醇及其烷基醚的合成与表征[J].化学研究与应用,2012,24(1):123-126. |
| 作者姓名： | 赵玲华 肖转泉 陈金珠 王宗德 范国荣 陈尚钘 |
| 作者单位： | 1. 江西农业大学林学院,江西南昌,330045 2. 江西师范大学化学化工学院,江西南昌,330027 3. 江西农业大学理学院,江西南昌,330045 |
| 基金项目： | 国家自然科学基金，教育部留学回国人员科研启动基金，江西省青年科学家(井冈之星)培养对象计划项目资助 |
| 摘 要： | 由β-蒎烯与多聚甲醛反应制得诺卜醇,然后用Ni(R)催化氢化制得氢化诺卜醇(ROH),再将氢化诺卜醇与亚硫酰氯反应制得氢化诺卜基氯(RCl),由RCl分别与6种醇钠反应合成了6种氢化诺卜基烷基醚,各产物的得率均在92%以上,GC纯度95%以上。各产物都用IR,1H NMR,13C NMR与MS进行了结构表征。 |
| 关 键 词： | 诺卜醇 氢化诺卜醇 氢化诺卜基氯 氢化诺卜基烷基醚 结构表征 |
Synthesis and identification of hydronopol and its alkyl ethers |
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| ZHAO Ling-hua , XIAO Zhuan-quan , CHEN Jin-zhu , WANG Zong-de , FAN Guo-rong , CHEN Shang-xing.Synthesis and identification of hydronopol and its alkyl ethers[J].Chemical Research and Application,2012,24(1):123-126. | |
| Authors: | ZHAO Ling-hua XIAO Zhuan-quan CHEN Jin-zhu WANG Zong-de FAN Guo-rong CHEN Shang-xing |
| Institution: | 1(1.College of Forestry,Jiangxi Agricultural University,Nanchang 330045,China; 2.College of Chemistry,Jiangxi Normal University,Nanchang 330027,China; 3.College of Science,Jiangxi Agricultural University,Nanchang 330045,China;) |
| Abstract: | Nopol was synthesized from β-pinene and paraformaldehyde,and hydronopol(ROH)was prepared from the hydrogenation of nopol in the presence of Raney Ni.Then hydronopyl chloride(RCl)was synthesized from hydronopol and thionyl chloride.Finally,six hydronopyl alkyl ethers were obtained from the reaction of hydronoply chloride and six different sodium alkoxides respectively.The yields of the six hydronoply alkyl ethers were all no less than 92%(GC content were over 95%).All the structures were indentified by IR,1H NMR,13C NMR and MS analysis. |
| Keywords: | nopol hydronopol hydronopyl chloride hydronoply alkyl ether structural identification |
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