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Stabilization and electron spin resonance characterization of Ru(bpy)3 and Ru(bpy)3 by radiolysis of Ru(bpy)3 adsorbed on silica gel
Authors:Kaoru Matsuura  Larry Kevan  
Institution:

a Research Reactor Institute, Kyoto University, Kumatori, Osaka 590-0494, Japan

b Department of Chemistry, University of Houston, Houston, TX 77204-5641, USA

Abstract:Ru(bpy)33+, which is important in artificial photosynthetic systems due to its high reduction potential, is stabilized together with its counter anion, Ru(bpy)3+, by radiolysis of Ru(bpy)32+ adsorbed on silica gel at 77 K. Both species are characterized by electron spin resonance.
Keywords:
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