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π-facial interactions between Cl and [S4N3]. X-ray crystal structure of [S4N3]Cl
Authors:José-Ramon Galan-Mascaros  Alexandra MZ Slawin  J Derek Woollins  David J Williams
Institution:Department of Chemistry, University of Valencia, Spain;Department of Chemistry, Loughborough University, Loughborough, Leics LE11 3TU, U.K.;Department of Chemistry, Imperial College, South Kensington, London SW7 2AY, U.K.
Abstract:The X-ray structure of S4N3]Cl reveals three independent molecules, which all display π-facial interactions between the Cl and the pseudo-aromatic S4N3]+ rings to produce a structure containing “inverse sandwich” systems.
Keywords:X-ray structure  sulfur  nitrogen  heterocycle  π-system  secondary interactions
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