Department of Chemistry, University of Valencia, Spain;Department of Chemistry, Loughborough University, Loughborough, Leics LE11 3TU, U.K.;Department of Chemistry, Imperial College, South Kensington, London SW7 2AY, U.K.
Abstract:
The X-ray structure of S4N3]Cl reveals three independent molecules, which all display π-facial interactions between the Cl− and the pseudo-aromatic S4N3]+ rings to produce a structure containing “inverse sandwich” systems.