Transition metal complexes with thiosemicarbazide-based ligands. Part LIV. Nickel(II) complexes with pyridoxal semi- (PLSC) and thiosemicarbazone (PLTSC). Crystal and molecular structure of [Ni(PLSC)(H2O)3](NO3)2 and [Ni(PLTSC-H)py]NO3 |
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Authors: | Vukadin M Leovac Ljiljana S Jovanovi? Vladimir Divjakovi? Andrej Pevec Ivan Leban Thomas Armbruster |
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Institution: | 1. Department of Chemistry, Faculty of Sciences, University of Novi Sad, Trg D. Obradovi?a 3, 21000 Novi Sad, Serbia;2. Department of Physics, Faculty of Sciences, University of Novi Sad, Trg D. Obradovi?a 3, 21000 Novi Sad, Serbia;3. Faculty of Chemistry and Chemical Technology, University of Ljubljana, Ašker?eva cesta 5, 1000 Ljubljana, Slovenia;4. Laboratory for Chemical and Mineralogical Crystallography, University of Bern, Freierstr. 3, CH-3012 Bern, Switzerland |
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Abstract: | This paper describes the synthesis of the first Ni(II) complexes with pyridoxal semicarbazone (PLSC), viz. Ni(PLSC)Cl2 · 3.5H2O (1), Ni(PLSC)(H2O)3](NO3)2 (2), Ni(PLSC)(NCS)2 · 4H2O (3), Ni(PLSC-2H)NH3] · 1.5H2O (4), as well as two new complexes with pyridoxal thiosemicarbazone (PLTSC), Ni(PLTSC-H)py]NO3 (5) and Ni(PLTSC-H)NCS] (6). Complexes 1–3 are paramagnetic and have most probably an octahedral structure, for complex 2 this was proved by X-ray diffraction analysis. In contrast, complexes 4–6 are diamagnetic and have a square-planar structure, and in the case of complex 5 this was also confirmed by X-ray structural analysis. In all cases the Schiff bases are coordinated as tridentate ligands with an ONX (X = O, PLSC; X = S, PLTSC) set of donor atoms. With the complexes involving the neutral form of PLSC and the monoanionic form of PLTSC, the PL moiety is in the form of a zwitterion. In addition to the above-mentioned techniques, all the complexes were characterized by measuring their molar conductivities, UV–Vis and partial IR spectra. |
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Keywords: | Ni(II) complexes Pyridoxal semi- and thiosemicarbazone Spectral characteristics X-ray analysis |
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