Allyldifluorophosphite-metal chemistry: Ru complexes of F2POC3H5 and the crystal structure of (Ph3P)2(F2POC3H5)Ru(CO)(Cl)H |
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| Authors: | John W Gilje Reinhard Schmutzler WS Sheldrick V Wray |
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| Institution: | Lehrstuhl B für Anorganische Chemie der Technischen Universität, Pockelsstrasse 4, D-3300 Braunschweig, West Germany;Gesellschaft für Biotechnologische Forschung mbH, Mascheroder Weg 1, D-3300 Braunschweig Stöckheim, West Germany |
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| Abstract: | With several chloro ruthenium phosphine complexes, allyldifluorophosphite, F2POC3H5, displaces triphenylphosphine to form new compounds in which it acts as a phosphorus donor ligand. The new complexes PPh3]2F2POC3H5]RuCO]Cl]H], I, and (PPh3)2(F2POC3H5)2RuCl2]nII, hav characterized by chemical, spectroscopic, and, in the case of I, crystallographic means. This behaviour of F2POC3H5 contrasts to its reactions with several platinum and palladium chloro complexes where it undergoes Arbuzov-type rearrangements. |
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| Keywords: | Authors to whom correspondence should be addressed |
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